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Chlorine monoxide

Also known as: Chlorine monoxide · Dichlorine monoxide · Dichlorine oxide · Oxygen dichloride

CAS No.
7791-21-1
Formula
Cl2O
Molar mass
86.9 g/mol
PubChem CID
24646
GHS pictograms
GHS pictogram: CorrosiveCorrosive
GHS pictogram: Environmental hazardEnvironmental hazard
2D structure of Chlorine monoxide
2D structure · PubChem CID 24646

Summary

Chlorine monoxide (Cl2O), CAS 7791-21-1. Common in labs and industry. Read on for hazards, storage, PPE and mixing rules.

Background

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Physical properties

2.2
2.2 °C
-120.6
-120.6 °C

Sourced from PubChem Experimental Properties. Values may vary between sources and conditions.

Hazards

GHS pictogram: Corrosive
Corrosive (GHS05)

Attacks skin, eyes and materials.

GHS pictogram: Environmental hazard
Environmental hazard (GHS09)

Toxic to aquatic organisms.

Hazard statements

Storage

Temperature

Keep at room temperature, below 30 °C, out of direct heat.

Ventilation

Store somewhere well-ventilated and away from any ignition source.

Containers

Metal drums or tinted glass, tightly sealed.

Keep away from

Strong acids, strong bases and powerful oxidizers.

Personal protective equipment

Gloves

Nitrile or butyl, at least 0.4 mm thick.

Eye protection

Safety goggles with side shields.

Respirator

A2 organic-vapor cartridge if the room isn't well ventilated.

Occupational exposure limits (HSE)

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EU harmonised classification (ECHA C&L)

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Transport

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FDA recalls & enforcement

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Compatibilities

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Practical safety notes

  • Corrosive. Wear chemical goggles, faceshield and chemical-resistant gloves. Have an eyewash within reach.
  • Environmental hazard. Do not release to sewers or waterways; collect for hazardous waste disposal.

Derived from the GHS classification shown above. These notes are generic guidance and do not replace the manufacturer's SDS or your local risk assessment.

FAQ

Is Chlorine monoxide flammable?+

Chlorine monoxide (CAS 7791-21-1) does not carry the GHS02 flame pictogram in our records. Always confirm with the manufacturer's SDS section 9 (flash point) before assuming a product is non-flammable.

What PPE should I wear when handling Chlorine monoxide?+

Chemical-splash goggles and a faceshield, chemical-resistant gloves (nitrile or butyl) and an apron are the minimum. Ventilation should be sufficient to keep vapours below the occupational exposure limit. Check SDS section 8 for material-specific breakthrough times.

How should Chlorine monoxide be stored?+

Store Chlorine monoxide (CAS 7791-21-1) in tightly closed original containers, in a cool, dry, well-ventilated area away from incompatible materials. Segregate acids from bases and keep away from metals that can be attacked.

Is Chlorine monoxide dangerous for the environment?+

Yes. Chlorine monoxide carries the GHS09 environment pictogram. Do not release to drains, soil or waterways; collect residues for hazardous-waste disposal in line with local regulations.

Where can I find the official Safety Data Sheet for Chlorine monoxide?+

Official, up-to-date SDS documents are published by each manufacturer (Sigma-Aldrich, Merck, Thermo Fisher, VWR, Carl Roth, etc.) and by regulators such as ECHA and NIOSH. This page is an educational summary and does not replace the manufacturer's SDS.

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