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Chloroacetaldehyde

Also known as: CHLOROACETALDEHYDE · 2-chloroacetaldehyde · 107-20-0 · Chloroethanal

CAS No.
107-20-0
Formula
C2H3ClO
Molar mass
78.5 g/mol
PubChem CID
33
GHS pictograms
GHS pictogram: FlammableFlammable
GHS pictogram: CorrosiveCorrosive
GHS pictogram: ToxicToxic
GHS pictogram: Health hazardHealth hazard
GHS pictogram: Environmental hazardEnvironmental hazard
2D structure of Chloroacetaldehyde
2D structure · PubChem CID 33

Summary

Chloroacetaldehyde (C2H3ClO), CAS 107-20-0. Common in labs and industry. Read on for hazards, storage, PPE and mixing rules.

Background

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Physical properties

85
185 °F at 760 mmHg (NTP, 1992)
-16.1
3 °F (USCG, 1999)
87.8
190 °F (NTP, 1992)
100
100 mmHg at 113 °F (40% aqueous solution) (NTP, 1992)
Vapor density(air = 1)
2.7
2.7 (40% aqueous solution) (NTP, 1992) - Heavier than air; will sink (Relative to Air)

Sourced from PubChem Experimental Properties. Values may vary between sources and conditions.

Hazards

Storage

Temperature

Keep at room temperature, below 30 °C, out of direct heat.

Ventilation

Store somewhere well-ventilated and away from any ignition source.

Containers

Metal drums or tinted glass, tightly sealed.

Keep away from

Strong acids, strong bases and powerful oxidizers.

Personal protective equipment

Gloves

Nitrile or butyl, at least 0.4 mm thick.

Eye protection

Safety goggles with side shields.

Respirator

A2 organic-vapor cartridge if the room isn't well ventilated.

Occupational exposure limits (HSE)

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EU harmonised classification (ECHA C&L)

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Transport

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FDA recalls & enforcement

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Compatibilities

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Practical safety notes

  • Flammable. Keep away from open flames, hot surfaces and sparks. Ground containers when transferring.
  • Corrosive. Wear chemical goggles, faceshield and chemical-resistant gloves. Have an eyewash within reach.
  • Acute toxicity. Work under a fume hood, restrict access, keep a specific antidote plan available.
  • Serious health hazard (carcinogen, mutagen, reprotoxic, respiratory sensitizer). Substitute if possible; otherwise closed systems and medical surveillance.
  • Environmental hazard. Do not release to sewers or waterways; collect for hazardous waste disposal.

Derived from the GHS classification shown above. These notes are generic guidance and do not replace the manufacturer's SDS or your local risk assessment.

FAQ

Is Chloroacetaldehyde flammable?+

Yes. Chloroacetaldehyde (CAS 107-20-0) carries the GHS02 flame pictogram. Keep it away from ignition sources, use non-sparking tools, and ground metal containers when transferring liquid.

What PPE should I wear when handling Chloroacetaldehyde?+

Chemical-splash goggles and a faceshield, chemical-resistant gloves (nitrile or butyl) and an apron are the minimum. Work inside a fume hood or use a suitable respirator. Check SDS section 8 for material-specific breakthrough times.

How should Chloroacetaldehyde be stored?+

Store Chloroacetaldehyde (CAS 107-20-0) in tightly closed original containers, in a cool, dry, well-ventilated area away from incompatible materials. Use a flammable-liquid cabinet and keep away from oxidizers and heat. Segregate acids from bases and keep away from metals that can be attacked.

Is Chloroacetaldehyde dangerous for the environment?+

Yes. Chloroacetaldehyde carries the GHS09 environment pictogram. Do not release to drains, soil or waterways; collect residues for hazardous-waste disposal in line with local regulations.

Where can I find the official Safety Data Sheet for Chloroacetaldehyde?+

Official, up-to-date SDS documents are published by each manufacturer (Sigma-Aldrich, Merck, Thermo Fisher, VWR, Carl Roth, etc.) and by regulators such as ECHA and NIOSH. This page is an educational summary and does not replace the manufacturer's SDS.

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