Educational content for trained professionals. Not a Safety Data Sheet, not medical advice. In an emergency, call your local poison control or emergency services immediately. Terms of use.

3,4-Dichlorophenyl isocyanate

Also known as: Isocyanic acid · 75-13-8 · Hydrogen isocyanate · HNCO

CAS No.
102-36-3
Formula
C7H3Cl2NO
Molar mass
188.01 g/mol
PubChem CID
7607
GHS pictograms
GHS pictogram: CorrosiveCorrosive
GHS pictogram: ToxicToxic
GHS pictogram: Harmful / IrritantHarmful / Irritant
GHS pictogram: Health hazardHealth hazard
2D structure of 3,4-Dichlorophenyl isocyanate
2D structure · PubChem CID 7607

Summary

3,4-Dichlorophenyl isocyanate (C7H3Cl2NO), CAS 102-36-3. Common in labs and industry. Read on for hazards, storage, PPE and mixing rules.

Background

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Hazards

GHS pictogram: Corrosive
Corrosive (GHS05)

Attacks skin, eyes and materials.

GHS pictogram: Toxic
Toxic (GHS06)

May be fatal even in small doses.

GHS pictogram: Harmful / Irritant
Harmful / Irritant (GHS07)

May cause skin, eye or respiratory irritation.

GHS pictogram: Health hazard
Health hazard (GHS08)

Serious long-term health effects (CMR, respiratory sensitizer).

Hazard statements

  • H301: Toxic if swallowed [Danger Acute toxicity, oral]
  • H315
  • H317
  • H319
  • H332: Harmful if inhaled [Warning Acute toxicity, inhalation]
  • H334
  • H335: May cause respiratory irritation [Warning Specific target organ toxicity, single exposure
  • H318: Causes serious eye damage [Danger Serious eye damage/eye irritation]
  • H330: Fatal if inhaled [Danger Acute toxicity, inhalation]

Storage

Temperature

Keep at room temperature, below 30 °C, out of direct heat.

Ventilation

Store somewhere well-ventilated and away from any ignition source.

Containers

Metal drums or tinted glass, tightly sealed.

Keep away from

Strong acids, strong bases and powerful oxidizers.

Personal protective equipment

Gloves

Nitrile or butyl, at least 0.4 mm thick.

Eye protection

Safety goggles with side shields.

Respirator

A2 organic-vapor cartridge if the room isn't well ventilated.

Occupational exposure limits (HSE)

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EU harmonised classification (ECHA C&L)

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Transport

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FDA recalls & enforcement

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Compatibilities

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Practical safety notes

  • Corrosive. Wear chemical goggles, faceshield and chemical-resistant gloves. Have an eyewash within reach.
  • Acute toxicity. Work under a fume hood, restrict access, keep a specific antidote plan available.
  • Irritant / harmful. Ventilate the workspace and avoid skin contact.
  • Serious health hazard (carcinogen, mutagen, reprotoxic, respiratory sensitizer). Substitute if possible; otherwise closed systems and medical surveillance.

Derived from the GHS classification shown above. These notes are generic guidance and do not replace the manufacturer's SDS or your local risk assessment.

FAQ

Is 3,4-Dichlorophenyl isocyanate flammable?+

3,4-Dichlorophenyl isocyanate (CAS 102-36-3) does not carry the GHS02 flame pictogram in our records. Always confirm with the manufacturer's SDS section 9 (flash point) before assuming a product is non-flammable.

What PPE should I wear when handling 3,4-Dichlorophenyl isocyanate?+

Chemical-splash goggles and a faceshield, chemical-resistant gloves (nitrile or butyl) and an apron are the minimum. Work inside a fume hood or use a suitable respirator. Check SDS section 8 for material-specific breakthrough times.

How should 3,4-Dichlorophenyl isocyanate be stored?+

Store 3,4-Dichlorophenyl isocyanate (CAS 102-36-3) in tightly closed original containers, in a cool, dry, well-ventilated area away from incompatible materials. Segregate acids from bases and keep away from metals that can be attacked.

Is 3,4-Dichlorophenyl isocyanate dangerous for the environment?+

No specific environmental pictogram (GHS09) is listed in our records for 3,4-Dichlorophenyl isocyanate, but any chemical waste should be handled through your site's hazardous-waste procedure, not poured down the drain.

Where can I find the official Safety Data Sheet for 3,4-Dichlorophenyl isocyanate?+

Official, up-to-date SDS documents are published by each manufacturer (Sigma-Aldrich, Merck, Thermo Fisher, VWR, Carl Roth, etc.) and by regulators such as ECHA and NIOSH. This page is an educational summary and does not replace the manufacturer's SDS.

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