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pentane

Also known as: PENTANE · n-Pentane · 109-66-0 · Pentan

CAS No.
109-66-0
Formula
C5H12
Molar mass
72.15 g/mol
PubChem CID
8003
GHS pictograms
GHS pictogram: FlammableFlammable
GHS pictogram: Harmful / IrritantHarmful / Irritant
GHS pictogram: Health hazardHealth hazard
GHS pictogram: Environmental hazardEnvironmental hazard
2D structure of pentane
2D structure · PubChem CID 8003

Summary

pentane (C5H12), CAS 109-66-0. Common in labs and industry. Read on for hazards, storage, PPE and mixing rules.

Background

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Hazards

GHS pictogram: Flammable
Flammable (GHS02)

Ignites easily when exposed to a flame or spark.

GHS pictogram: Harmful / Irritant
Harmful / Irritant (GHS07)

May cause skin, eye or respiratory irritation.

GHS pictogram: Health hazard
Health hazard (GHS08)

Serious long-term health effects (CMR, respiratory sensitizer).

GHS pictogram: Environmental hazard
Environmental hazard (GHS09)

Toxic to aquatic organisms.

Hazard statements

  • H225: Highly Flammable liquid and vapor [Danger Flammable liquids]
  • H304: May be fatal if swallowed and enters airways [Danger Aspiration hazard]
  • H336: May cause drowsiness or dizziness [Warning Specific target organ toxicity, single exposure
  • H411: Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]
  • H224
  • H320: Causes eye irritation [Warning Serious eye damage/eye irritation]
  • H335: May cause respiratory irritation [Warning Specific target organ toxicity, single exposure
  • H401: Toxic to aquatic life [Hazardous to the aquatic environment, acute hazard]

Storage

Temperature

Keep at room temperature, below 30 °C, out of direct heat.

Ventilation

Store somewhere well-ventilated and away from any ignition source.

Containers

Metal drums or tinted glass, tightly sealed.

Keep away from

Strong acids, strong bases and powerful oxidizers.

Personal protective equipment

Gloves

Nitrile or butyl, at least 0.4 mm thick.

Eye protection

Safety goggles with side shields.

Respirator

A2 organic-vapor cartridge if the room isn't well ventilated.

Occupational exposure limits (HSE)

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EU harmonised classification (ECHA C&L)

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Transport

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FDA recalls & enforcement

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Compatibilities

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Practical safety notes

  • Flammable. Keep away from open flames, hot surfaces and sparks. Ground containers when transferring.
  • Irritant / harmful. Ventilate the workspace and avoid skin contact.
  • Serious health hazard (carcinogen, mutagen, reprotoxic, respiratory sensitizer). Substitute if possible; otherwise closed systems and medical surveillance.
  • Environmental hazard. Do not release to sewers or waterways; collect for hazardous waste disposal.

Derived from the GHS classification shown above. These notes are generic guidance and do not replace the manufacturer's SDS or your local risk assessment.

FAQ

Is pentane flammable?+

Yes. pentane (CAS 109-66-0) carries the GHS02 flame pictogram. Keep it away from ignition sources, use non-sparking tools, and ground metal containers when transferring liquid.

What PPE should I wear when handling pentane?+

Safety glasses with side shields and nitrile gloves are the baseline. Work inside a fume hood or use a suitable respirator. Check SDS section 8 for material-specific breakthrough times.

How should pentane be stored?+

Store pentane (CAS 109-66-0) in tightly closed original containers, in a cool, dry, well-ventilated area away from incompatible materials. Use a flammable-liquid cabinet and keep away from oxidizers and heat.

Is pentane dangerous for the environment?+

Yes. pentane carries the GHS09 environment pictogram. Do not release to drains, soil or waterways; collect residues for hazardous-waste disposal in line with local regulations.

Where can I find the official Safety Data Sheet for pentane?+

Official, up-to-date SDS documents are published by each manufacturer (Sigma-Aldrich, Merck, Thermo Fisher, VWR, Carl Roth, etc.) and by regulators such as ECHA and NIOSH. This page is an educational summary and does not replace the manufacturer's SDS.

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