Educational content for trained professionals. Not a Safety Data Sheet, not medical advice. In an emergency, call your local poison control or emergency services immediately. Terms of use.
sodium azide
Also known as: sodium azide · 26628-22-8 · Azide, sodium · Natriumazid
- CAS No.
- 26628-22-8
- Formula
- N3Na
- Molar mass
- 65.01 g/mol
- PubChem CID
- 33557
Corrosive
Toxic
Health hazard
Environmental hazard
Summary
sodium azide (N3Na), CAS 26628-22-8. Common in labs and industry. Read on for hazards, storage, PPE and mixing rules.
Background
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Physical properties
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Hazards
Attacks skin, eyes and materials.
May be fatal even in small doses.
Serious long-term health effects (CMR, respiratory sensitizer).
Toxic to aquatic organisms.
Hazard statements
- H300: Fatal if swallowed [Danger Acute toxicity, oral]
- H400: Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
- H410: Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]
- H310: Fatal in contact with skin [Danger Acute toxicity, dermal]
- H373: May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure]
- H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
- H318: Causes serious eye damage [Danger Serious eye damage/eye irritation]
- H370: Causes damage to organs [Danger Specific target organ toxicity, single exposure]
- H372: Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]
Storage
Keep at room temperature, below 30 °C, out of direct heat.
Store somewhere well-ventilated and away from any ignition source.
Metal drums or tinted glass, tightly sealed.
Strong acids, strong bases and powerful oxidizers.
Personal protective equipment
Nitrile or butyl, at least 0.4 mm thick.
Safety goggles with side shields.
A2 organic-vapor cartridge if the room isn't well ventilated.
Occupational exposure limits (HSE)
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EU harmonised classification (ECHA C&L)
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Transport
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Compatibilities
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Open comparator with sodium azidePractical safety notes
- Corrosive. Wear chemical goggles, faceshield and chemical-resistant gloves. Have an eyewash within reach.
- Acute toxicity. Work under a fume hood, restrict access, keep a specific antidote plan available.
- Serious health hazard (carcinogen, mutagen, reprotoxic, respiratory sensitizer). Substitute if possible; otherwise closed systems and medical surveillance.
- Environmental hazard. Do not release to sewers or waterways; collect for hazardous waste disposal.
Derived from the GHS classification shown above. These notes are generic guidance and do not replace the manufacturer's SDS or your local risk assessment.
FAQ
Is sodium azide flammable?+
sodium azide (CAS 26628-22-8) does not carry the GHS02 flame pictogram in our records. Always confirm with the manufacturer's SDS section 9 (flash point) before assuming a product is non-flammable.
What PPE should I wear when handling sodium azide?+
Chemical-splash goggles and a faceshield, chemical-resistant gloves (nitrile or butyl) and an apron are the minimum. Work inside a fume hood or use a suitable respirator. Check SDS section 8 for material-specific breakthrough times.
How should sodium azide be stored?+
Store sodium azide (CAS 26628-22-8) in tightly closed original containers, in a cool, dry, well-ventilated area away from incompatible materials. Segregate acids from bases and keep away from metals that can be attacked.
Is sodium azide dangerous for the environment?+
Yes. sodium azide carries the GHS09 environment pictogram. Do not release to drains, soil or waterways; collect residues for hazardous-waste disposal in line with local regulations.
Where can I find the official Safety Data Sheet for sodium azide?+
Official, up-to-date SDS documents are published by each manufacturer (Sigma-Aldrich, Merck, Thermo Fisher, VWR, Carl Roth, etc.) and by regulators such as ECHA and NIOSH. This page is an educational summary and does not replace the manufacturer's SDS.
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