Educational content for trained professionals. Not a Safety Data Sheet, not medical advice. In an emergency, call your local poison control or emergency services immediately. Terms of use.
sulfuryl fluoride
Also known as: SULFURYL FLUORIDE · Sulfuryl difluoride · Sulfonyl fluoride · 2699-79-8
- CAS No.
- 2699-79-8
- Formula
- F2O2S
- Molar mass
- 102.06 g/mol
- PubChem CID
- 17607
Summary
sulfuryl fluoride (F2O2S), CAS 2699-79-8. Common in labs and industry. Read on for hazards, storage, PPE and mixing rules.
Background
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Physical properties
No experimental physical properties indexed yet. Try PubChem for the raw record.
Hazards
Contents under pressure, may explode if heated.
May be fatal even in small doses.
May cause skin, eye or respiratory irritation.
Serious long-term health effects (CMR, respiratory sensitizer).
Toxic to aquatic organisms.
Hazard statements
- H331: Toxic if inhaled [Danger Acute toxicity, inhalation]
- H373: May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure]
- H400: Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
- H280: Contains gas under pressure
- H330
- H370: Causes damage to organs [Danger Specific target organ toxicity, single exposure]
- H301: Toxic if swallowed [Danger Acute toxicity, oral]
- H315: Causes skin irritation [Warning Skin corrosion/irritation]
- H319: Causes serious eye irritation [Warning Serious eye damage/eye irritation]
- H371: May cause damage to organs [Warning Specific target organ toxicity, single exposure]
Storage
Keep at room temperature, below 30 °C, out of direct heat.
Store somewhere well-ventilated and away from any ignition source.
Metal drums or tinted glass, tightly sealed.
Strong acids, strong bases and powerful oxidizers.
Personal protective equipment
Nitrile or butyl, at least 0.4 mm thick.
Safety goggles with side shields.
A2 organic-vapor cartridge if the room isn't well ventilated.
Occupational exposure limits (HSE)
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EU harmonised classification (ECHA C&L)
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Transport
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FDA recalls & enforcement
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Compatibilities
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Open comparator with sulfuryl fluoridePractical safety notes
- Compressed gas. Secure cylinders upright, protect valves, store in ventilated areas.
- Acute toxicity. Work under a fume hood, restrict access, keep a specific antidote plan available.
- Irritant / harmful. Ventilate the workspace and avoid skin contact.
- Serious health hazard (carcinogen, mutagen, reprotoxic, respiratory sensitizer). Substitute if possible; otherwise closed systems and medical surveillance.
- Environmental hazard. Do not release to sewers or waterways; collect for hazardous waste disposal.
Derived from the GHS classification shown above. These notes are generic guidance and do not replace the manufacturer's SDS or your local risk assessment.
FAQ
Is sulfuryl fluoride flammable?+
sulfuryl fluoride (CAS 2699-79-8) does not carry the GHS02 flame pictogram in our records. Always confirm with the manufacturer's SDS section 9 (flash point) before assuming a product is non-flammable.
What PPE should I wear when handling sulfuryl fluoride?+
Safety glasses with side shields and nitrile gloves are the baseline. Work inside a fume hood or use a suitable respirator. Check SDS section 8 for material-specific breakthrough times.
How should sulfuryl fluoride be stored?+
Store sulfuryl fluoride (CAS 2699-79-8) in tightly closed original containers, in a cool, dry, well-ventilated area away from incompatible materials.
Is sulfuryl fluoride dangerous for the environment?+
Yes. sulfuryl fluoride carries the GHS09 environment pictogram. Do not release to drains, soil or waterways; collect residues for hazardous-waste disposal in line with local regulations.
Where can I find the official Safety Data Sheet for sulfuryl fluoride?+
Official, up-to-date SDS documents are published by each manufacturer (Sigma-Aldrich, Merck, Thermo Fisher, VWR, Carl Roth, etc.) and by regulators such as ECHA and NIOSH. This page is an educational summary and does not replace the manufacturer's SDS.
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