Educational content for trained professionals. Not a Safety Data Sheet, not medical advice. In an emergency, call your local poison control or emergency services immediately. Terms of use.

Tert-butyl peroxyisopropyl carbonate

Also known as: 2372-21-6 · (2-methylpropan-2-yl)oxy propan-2-yl carbonate · Carbonoperoxoic acid, OO-(1,1-dimethylethyl) O-(1-methylethyl) ester · 65CY7NX9N8

CAS No.
2372-21-6
Formula
C8H16O4
Molar mass
176.21 g/mol
PubChem CID
75406
GHS pictograms
GHS pictogram: ExplosiveExplosive
GHS pictogram: FlammableFlammable
GHS pictogram: CorrosiveCorrosive
GHS pictogram: Harmful / IrritantHarmful / Irritant
GHS pictogram: Environmental hazardEnvironmental hazard
2D structure of Tert-butyl peroxyisopropyl carbonate
2D structure · PubChem CID 75406

Summary

Tert-butyl peroxyisopropyl carbonate (C8H16O4), CAS 2372-21-6. Common in labs and industry. Read on for hazards, storage, PPE and mixing rules.

Background

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Physical properties

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Hazards

GHS pictogram: Explosive
Explosive (GHS01)

May explode when exposed to heat, shock or flame.

GHS pictogram: Flammable
Flammable (GHS02)

Ignites easily when exposed to a flame or spark.

GHS pictogram: Corrosive
Corrosive (GHS05)

Attacks skin, eyes and materials.

GHS pictogram: Harmful / Irritant
Harmful / Irritant (GHS07)

May cause skin, eye or respiratory irritation.

GHS pictogram: Environmental hazard
Environmental hazard (GHS09)

Toxic to aquatic organisms.

Storage

Temperature

Keep at room temperature, below 30 °C, out of direct heat.

Ventilation

Store somewhere well-ventilated and away from any ignition source.

Containers

Metal drums or tinted glass, tightly sealed.

Keep away from

Strong acids, strong bases and powerful oxidizers.

Personal protective equipment

Gloves

Nitrile or butyl, at least 0.4 mm thick.

Eye protection

Safety goggles with side shields.

Respirator

A2 organic-vapor cartridge if the room isn't well ventilated.

Occupational exposure limits (HSE)

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EU harmonised classification (ECHA C&L)

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Transport

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FDA recalls & enforcement

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Compatibilities

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Practical safety notes

  • Explosive. Keep away from shock, friction, sparks and heat. Store in dedicated magazines.
  • Flammable. Keep away from open flames, hot surfaces and sparks. Ground containers when transferring.
  • Corrosive. Wear chemical goggles, faceshield and chemical-resistant gloves. Have an eyewash within reach.
  • Irritant / harmful. Ventilate the workspace and avoid skin contact.
  • Environmental hazard. Do not release to sewers or waterways; collect for hazardous waste disposal.

Derived from the GHS classification shown above. These notes are generic guidance and do not replace the manufacturer's SDS or your local risk assessment.

FAQ

Is Tert-butyl peroxyisopropyl carbonate flammable?+

Yes. Tert-butyl peroxyisopropyl carbonate (CAS 2372-21-6) carries the GHS02 flame pictogram. Keep it away from ignition sources, use non-sparking tools, and ground metal containers when transferring liquid.

What PPE should I wear when handling Tert-butyl peroxyisopropyl carbonate?+

Chemical-splash goggles and a faceshield, chemical-resistant gloves (nitrile or butyl) and an apron are the minimum. Ventilation should be sufficient to keep vapours below the occupational exposure limit. Check SDS section 8 for material-specific breakthrough times.

How should Tert-butyl peroxyisopropyl carbonate be stored?+

Store Tert-butyl peroxyisopropyl carbonate (CAS 2372-21-6) in tightly closed original containers, in a cool, dry, well-ventilated area away from incompatible materials. Use a flammable-liquid cabinet and keep away from oxidizers and heat. Segregate acids from bases and keep away from metals that can be attacked.

Is Tert-butyl peroxyisopropyl carbonate dangerous for the environment?+

Yes. Tert-butyl peroxyisopropyl carbonate carries the GHS09 environment pictogram. Do not release to drains, soil or waterways; collect residues for hazardous-waste disposal in line with local regulations.

Where can I find the official Safety Data Sheet for Tert-butyl peroxyisopropyl carbonate?+

Official, up-to-date SDS documents are published by each manufacturer (Sigma-Aldrich, Merck, Thermo Fisher, VWR, Carl Roth, etc.) and by regulators such as ECHA and NIOSH. This page is an educational summary and does not replace the manufacturer's SDS.

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